𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The Mechanism of the Diazo-Coupling Reaction Part IV-The Decomposition of Diazotised Aniline at Different pH Values

✍ Scribed by Hodgson, H. H. ;Marsden, E.

Book ID
115298000
Publisher
Wiley (Blackwell Publishing)
Year
2008
Tongue
English
Weight
273 KB
Volume
61
Category
Article
ISSN
0037-9859

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Mechanisms of Diazo Coupling Reactions.
Mechanisms of Diazo Coupling Reactions. Part XXXII. The Diazoamino Rearrangement in 20% Acetonitrile/Aqueous Buffers
✍ Richard P. Kelly; John R. Penton; Heinrich Zollinger 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 German ⚖ 591 KB

## Abstract The rearrangements of 4′‐methoxy‐__N__‐methyl‐ and __N__‐methyl‐4′‐nitro‐diatzoaminobenzene have been studied in 20% acetonitrile/aqueous buffers. The reactions are specifically acid catalyzed and involve pre‐equilibrium formation of amine and diazonium salt followed by rate‐limiting at

The radical coupling mechanism in the di
The radical coupling mechanism in the diazo coupling reaction. Migration vs. decomposition of phenylazo radical generated from phenylazo 1-naphthyl ether in the solvent cage
✍ Takahiro Tezuka; Hiroharu Tanikawa; Katsunori Sasaki; Harumi Tajima 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 258 KB

The thermal reaction of phenylazo I-naphthyl ether generates a pair of phenylazo and naphthoxy radicals in the solvent cage, in which these radicals couple together at the aromatic carbon to give 4-phenylazo-I-naphthol and 2-phenylazo-I-naphthol.

Mechanisms of Diazo Coupling Reactions.
Mechanisms of Diazo Coupling Reactions. Part XXXI. Aminoazo formation in the diazo coupling of N, N-dimethylaniline and m-toluidine with p-methoxybenzenediazonium tetrafluoroborate in acetonitrile
✍ John R. Penton; Heinrich Zollinger 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 German ⚖ 615 KB

## Abstract In the title reactions it is shown that aminoazo formation does not occur by direct attack of diazonium ion at C‐atom. Initial attack is at N‐atom, but proton loss from the ω~N~‐complex formed is relatively slow. Hence, at low amine concentration this rearranges intermolecularly to the