✦ LIBER ✦
The radical coupling mechanism in the diazo coupling reaction. Migration vs. decomposition of phenylazo radical generated from phenylazo 1-naphthyl ether in the solvent cage
✍ Scribed by Takahiro Tezuka; Hiroharu Tanikawa; Katsunori Sasaki; Harumi Tajima
- Book ID
- 104229738
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- French
- Weight
- 258 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
The thermal reaction of phenylazo I-naphthyl ether generates a pair of phenylazo and naphthoxy radicals in the solvent cage, in which these radicals couple together at the aromatic carbon to give 4-phenylazo-I-naphthol and 2-phenylazo-I-naphthol.