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The mechanism of the acid-catalyzed dehydration of 1,2-diphenylethanol

✍ Scribed by Noyce, Donald S.; Hartter, Donald R.; Pollack, Ralph M.


Book ID
126219633
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
500 KB
Volume
90
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES


Conformational effects on the mechanism
✍ Lj. DoΕ‘en-MiΔ‡oviΔ‡; Ε½. ČekoviΔ‡ πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 94 KB πŸ‘ 2 views

The Monte Carlo search of the low-energy regions of D-mannitol (4) and D-glucitol (5) conformational space was undertaken in order to investigate conformational effects on the stereochemistry of the acid-catalyzed dehydrative cyclization reaction of 4 and 5 to the corresponding 1,4:3,6-dianhydrohexi

Mechanism and kinetics of the acid-catal
✍ Xiaodong Xu; Carlos De Almeida; Michael J. Antal Jr. πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 English βš– 472 KB

In the presence of a low concentration (<O.Ol mol dm-3) of sulfuric acid, ethanol undergoes rapid and selective dehydration to ethene in supercritical water. The kinetics of this reaction are consistent with an acid-catalyzed E2 mechanism.