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The mechanism of S1 [fx403-1] T1 nonradiative process in quinoxaline by Zeeman-PMDR spectroscopy

✍ Scribed by Paul E. Zinsli; M.A. El-Sayed

Publisher: Elsevier Science
Year: 1975
Tongue: English
Weight: 470 KB
Volume: 34
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(75)85524-2

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✦ Synopsis

It is demonstrated that the results of the Zeemzn effect on the observed phosphorescence spectrum at lo-3 temperatures can yield information concerning the mechanism of the St 4 Tl nonradiative process. The results of this s well a the ikeman-PMDR technique support the direct SI(n,r;*) 4 Tl(n,n*) intersystem crossing mechanism for quinoxa!ine in durene, in spite of the larger energy gap involved (as compared with the St 4 T2 3 TL mechanism).

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