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The mechanism of pyrolysis of cyclopropanes. Racemization and geometrical isomerization of tetramethylcyclopropane-d6

✍ Scribed by Berson, Jerome A.; Balquist, James M.


Book ID
126330671
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
260 KB
Volume
90
Category
Article
ISSN
0002-7863

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## Abstract Reaction rates for the structural isomerization of 1,1,2,2‐tetramethylcyclopropane to 2,4‐dimethyl‐2‐pentene have been measured over a wide temperature range, 672–750 K in a static reactor and 1000–1120 K in a single‐pulse shock tube. The combined data from the two temperature regions g