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The Mechanism of Polymerization of Butadiene by “Ligand-Free” Nickel(II) Complexes

✍ Scribed by O'Connor, Abby R.; White, Peter S.; Brookhart, Maurice

Book ID
120464671
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
81 KB
Volume
129
Category
Article
ISSN
0002-7863

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Investigation of the mechanism of polyme
Investigation of the mechanism of polymerization of butadiene by π-allylic nickel complexes
✍ Bourdauducq, P. ;Dawans, F. 📂 Article 📅 1972 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 842 KB

## Abstract Various π‐allylic nickel complexes were synthesized by reacting bis(1,5‐cyclooctadiene)‐nickel with an allylic ester of trifluoroacetic acid. A study of the stereospecific polymerization of 1,3‐butadiene initiated by these catalysts showed the strong influence of the initial substitutio