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The Mechanism of Photochemical 1,3-Silyl Migration of Allylsilane

โœ Scribed by Takahashi, Masae


Book ID
126024041
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
127 KB
Volume
109
Category
Article
ISSN
1089-5639

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Photochemical generation of tetramethyld
โœ Yasuhiro Nakadaira; Tatsuo Otsuka; Hideki Sakurai ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 223 KB

Described herein is the first clear evidence of the photochemical generation of tetramethyldisilene which can be efficiently trapped by dienes. An intriguing 1,2-photo-induced silyl migration is also reported. Roak and Peddle have demonstrated for the first time the transient existence of reactive t