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Silyl Migration in the Photochemical Reactions of 2-Trimethylsilylmethylphenyl Ketones

โœ Scribed by Saito, Masaichi; Saito, Akitomo; Ishikawa, Yuko; Yoshioka, Michikazu


Book ID
126121447
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
38 KB
Volume
7
Category
Article
ISSN
1523-7060

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Reactions of silyl cations with ketones
โœ Leblanc, D.; Audier, H. E.; Denhez, J. P. ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 85 KB ๐Ÿ‘ 2 views

In the gas phase, (CH 3 ) 3 SiOSi Y (CH 3 ) 2 and (CH 3 )CH 2 SiOSi Y (CH 3 ) 2 ions 1 and 2 were formed in the external source of a Fourier transform ion cyclofrom resonance (FT-ICR) spectrometer by electron impact ionization of (CH 3 ) 3 SiOSi(CH 3 ) 3 . In the FT-ICR cell, the electrophilic cente