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The mechanism of O3-aldehyde reactions

✍ Scribed by Richard I. Martinez

Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
576 KB
Volume
14
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

A new mechanism is proposed for gas‐phase O~3~‐aldehyde reactions. Certain aspects of the new mechanism may be applicable also to O~3~‐aldehyde reactions in solution. The proposed mechanism involves initiation by addition of O~3~ across the aldehydic CO bond. The initiation process and the subsequent chemistry together represent an exact analogue of the Criegee mechanism for O~3~‐alkene reactions.

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