Mechanism of the (O---H---O) hydrogen transfer in ene reactions
✍ Scribed by Rhida Ben Salem; Gérard Jenner
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 138 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
## Abstract The kinetics of the hydrogen abstraction from H~2~O~2~ by ^•^OH has been modeled with MP2/6‐31G\*//MP2/6‐31G\*, MP2‐SAC//MP2/6‐31G\*, MP2/6‐31+G\*\*//MP2/6‐31+G\*\*, MP2‐SAC// MP2/6‐31+G\*\*, MP4(SDTQ)/6‐311G\*\*//MP2/6‐31G\*, CCSD(T)/6‐31G\*//CCSD(T)/6‐31G\*, CCSD(T)/6‐31G\*\*//CCSD(T)
## Abstract A new mechanism is proposed for gas‐phase O~3~‐aldehyde reactions. Certain aspects of the new mechanism may be applicable also to O~3~‐aldehyde reactions in solution. The proposed mechanism involves initiation by addition of O~3~ across the aldehydic CO bond. The initiation process and