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The mechanism of kinetic oscillations in the NO + CO reaction on Pt(100)

✍ Scribed by Th. Fink; J.-P. Dath; R. Imbihl; G. Ertl

Book ID: 118364716
Publisher: Elsevier Science
Year: 1991
Tongue: English
Weight: 412 KB
Volume: 251-252
Category: Article
ISSN: 0039-6028
DOI: 10.1016/0039-6028(91)91137-m

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It is shown that the reaction between NO and CO on Pt(100) is autocatalytic and probably involves a surface species which accelerates the reaction. Temperature-programmed desorption (TPD) of co-adsorbed NO and CO yields complete reaction, with N2 and CO2 desorbing simultaneously in sharp peaks at =4