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The mechanism of kinetic oscillations in the NO + CO reaction on Pt(100)

โœ Scribed by Th. Fink; J.-P. Dath; R. Imbihl; G. Ertl


Publisher
Elsevier Science
Year
1991
Weight
65 KB
Volume
251-252
Category
Article
ISSN
0167-2584

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๐Ÿ“œ SIMILAR VOLUMES


The NO + CO reaction on Pt(100)
โœ M.W. Lesley; L.D. Schmidt ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science โš– 51 KB
Chemical autocatalysis in the NO + CO re
โœ M.W. Lesley; L.D. Schmidt ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 547 KB

It is shown that the reaction between NO and CO on Pt(100) is autocatalytic and probably involves a surface species which accelerates the reaction. Temperature-programmed desorption (TPD) of co-adsorbed NO and CO yields complete reaction, with N2 and CO2 desorbing simultaneously in sharp peaks at =4