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The mechanism of initiation by aluminium trichloride of cationic ethylene polymerization

โœ Scribed by P.Ye. Matkovskii; V.N. Belova; F.S. Dy'achkovskii

Book ID
118965123
Publisher
Elsevier Science
Year
1976
Weight
292 KB
Volume
18
Category
Article
ISSN
0032-3950

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Cationic polymerization of styrene initi
Cationic polymerization of styrene initiated by phosphorus trichloride
โœ Takumi Taninaka; Yuji Minoura ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 378 KB

Cationic polymerization of styrene(St) initiated by phosphorus trichloride(PC13) in nitrobenzene was carried out at 30 ยฐ. The initial rate was proportional to [St] 2 and [PCl3]. The overall activation energy was about 10.4 kcal/mole. The rate and the degree of polymerization were enhanced with incre