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The mechanism of formation of the hydroperoxyl radical in the CF3COOH +3O2system: a quantum-chemical study

✍ Scribed by V. N. Solkan; G. M. Zhidomirov; M. Ya. Mel’nikov

Book ID
111472718
Publisher
Pleiades Publishing
Year
2010
Tongue
English
Weight
233 KB
Volume
4
Category
Article
ISSN
1990-7931

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A kinetic study of the CF3CFHO2 + NO rea
A kinetic study of the CF3CFHO2 + NO reaction and the dissociation of the CF3CFHO radical
✍ Ashish Bhatnagar; Robert W. Carr 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 582 KB

The kinetics of the reaction of CF,CFHO, radicals with NO was studied by flash photolysis-time-resolved mass spectrometry. From the kinetic growth rate of NO: molecular ions the rate coefficient of the reaction CF,CFHO, + NO -+ CF,CFHO + NO, was determined to be k = (1.31 &-0.30) X 10-l' cm3 molecul