The reaction of CF, with NO, was studied at 296 2 2 K using two different absolute techniques Absolute rate constants of ( I 6 ? 0.3) X lo-" and ( 2 1-03+07) X lo-" cm3 molecule-' s-' were derived by IR fluorescence and UV absorption spectroscopy, respectively The reaction proceeds via two reaction
A Systematic Investigation into the Mechanism of the Reaction Between CF3 Radicals and CO/O2
✍ Scribed by Maximiliano A. Burgos Paci; Gustavo A. Argüello
- Publisher
- John Wiley and Sons
- Year
- 2004
- Tongue
- English
- Weight
- 186 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0947-6539
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## Abstract By means of the dual‐level direct dynamics method, the mechanisms of the reactions, CH~3~CF~2~Cl + OH → products (R1) and CH~3~CFCl~2~ + OH → products (R2), are studied over a wide temperature range 200–2000 K. The optimized geometries and frequencies of the stationary points are calcul