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The Mechanism of Cis − Trans Isomerization of Prolyl Peptides by Cyclophilin

✍ Scribed by Hur, Sun; Bruice, Thomas C.


Book ID
126114999
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
595 KB
Volume
124
Category
Article
ISSN
0002-7863

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Cis–Trans isomerism of the peptide bond
✍ P. R. Andrews 📂 Article 📅 1971 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 740 KB

The molecrilar orbital method PC'IIN is applied 10 eight N-n~ot~osi~bstituted amides. Experimentally known geometric properties are reasoilably predicted by minimization of total energy with respect to molecular geometry. The bame procedure shows that molecular deformations during rotation around t