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Mechanism of cis-trans isomerizations of amide and peptide excited states

✍ Scribed by Li, Yi; Garrell, Robin L.; Houk, K. N.

Book ID
120344901
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
268 KB
Volume
113
Category
Article
ISSN
0002-7863

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Cis–Trans isomerism of the peptide bond
Cis–Trans isomerism of the peptide bond
✍ P. R. Andrews πŸ“‚ Article πŸ“… 1971 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 740 KB

The molecrilar orbital method PC'IIN is applied 10 eight N-n~ot~osi~bstituted amides. Experimentally known geometric properties are reasoilably predicted by minimization of total energy with respect to molecular geometry. The bame procedure shows that molecular deformations during rotation around t