The mechanism of chain termination in the free-radical polymerization of vinyl chloride by 14C-labelled initiators
β Scribed by G.A. Razuvayev; G.G. Petukhov; V.A. Dodonov
- Book ID
- 118355242
- Publisher
- Elsevier Science
- Year
- 1962
- Weight
- 364 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0032-3950
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The rate of vinyl chloride polymerization initiated by doubly labelled benzoyl peroxide in dichloroethane at 60 Β° was measured dilatometrically. The extent of primary radical termination, evaluated from the assay of the polymer samples recovered at 10% conversion, is compared with values deduced fro
A~traet A numeric solution is developed for a kinetic scheme involving chain length dependent termination (by disproportionation) and chain transfer on the basis of the harmonic and the geometric mean approximation for the two radicals involved in the termination process. In addition, solutions in t