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THE MECHANISM OF CARBOHYDRATE OXIDATION. III. THE OXIDATION OF THE HEXITOLS d-MANNITOL, d-SORBITOL AND DULCITOL

✍ Scribed by Evans, William Lloyd; Holl, Carl Waldo

Book ID
121277702
Publisher
American Chemical Society
Year
1925
Tongue
English
Weight
271 KB
Volume
47
Category
Article
ISSN
0002-7863

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## Abstract The kinetics and mechanism of cerium(IV) oxidation of hexitols, i.e. D‐sorbitol and D‐mannitol, in aqueous sulfuric acid media have been studied in the presence and absence of surfactants. Under the kinetic conditions, [S]~T~ ≫ [Ce(IV)]~T~, where [S]~T~ is the total substrate (D‐sorbito