Kinetics and mechanism of ruthenium(III) catalysis in the oxidation of erythritol and dulcitol byN-bromoacetamide
โ Scribed by Bharat Singh; Deepika Singh; Shalini Bajpai; Ashutosh Kumar
- Publisher
- Springer
- Year
- 1991
- Tongue
- English
- Weight
- 340 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0340-4285
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๐ SIMILAR VOLUMES
In aqueous solutions, [Cr(en)3] 3+ aquates to [Cr(en)z-(H20)2] 3 ยง A kinetic study of the oxidation of [Cr(en)3] 3+ by N-bromosuccinimide (NBS)in aqueous solutions and water-alcohol solvent mixtures was performed. The reaction is first order with respect to both total [Cr m] and [NBS]. The rate is i
Kinetics of oxidation of ethylene glycol and glycerol by acidic solution of Nbromoacetamide (NBAI in the presence of ruthenium (111) chloride as a homogeneous catalyst and mercuric acetate as scavenger in the temperature range of 30-50ยฐC have been reported. The reactions follow identical kinetics, b