In aqueous solutions, [Cr(en)3] 3+ aquates to [Cr(en)z-(H20)2] 3 Β§ A kinetic study of the oxidation of [Cr(en)3] 3+ by N-bromosuccinimide (NBS)in aqueous solutions and water-alcohol solvent mixtures was performed. The reaction is first order with respect to both total [Cr m] and [NBS]. The rate is i
Kinetics and mechanism of oxidation of (aqua-2-aminomethyl-pyridine) chromium(III) byN-bromosuccinimide
β Scribed by Ayed S. M. Al-Shihri; Alaa El-Din M. Abdel-Hady
- Publisher
- Springer
- Year
- 1996
- Tongue
- English
- Weight
- 339 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0340-4285
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## Abstract The kinetics of oxidation of [Cr^III^(Dpc)(Asp)(H~2~O)~2~] (Dpc = dipicolinic acid and Asp = DLβaspartic acid) by __N__βbromosuccinimide (NBS) in aqueous solution have been found to obey the equation: equation image where __k__~2~ is the rate constant for the electron transfer process