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The McFadyen-Stevens synthesis of aliphatic aldehydes containing α-hydrogens

✍ Scribed by Harry Babad; Washington Herbert; Arthur W. Stiles

Book ID: 104250320
Publisher: Elsevier Science
Year: 1966
Tongue: French
Weight: 216 KB
Volume: 7
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)99889-2

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✦ Synopsis

The alkaline decomposition of l-acyl-2-arylsulfonylhydrazines to yield aldehydes was first described by McFadyen and Stevens (1) And A ccmprehensive review of the reaction has since been published (2). + OH-+ HCHO + ArSOA-+ NA + HA0 The work of McFAdyen And Stevens (1,2) established that the method WAA applicable, in varying yields, only to the preparation of Aromatic and heteracyclic aldehydes. Recently Sprecher (3) extended this reaction to the aliphatic series for compounds having no hydrOgAII AtDIAA on the

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