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The chemistry and catalytic properties of ruthenium and osmium complexes. Part 5. Synthesis of new compounds containing arsine ligands and catalytic activity in the homogeneous hydrogenation of aldehydes

✍ Scribed by Roberto A. Sanchez-Delgado; Wonyong Lee; Sung Rack Choi; Yangha Cho; Moo-Jin Jun


Publisher
Springer
Year
1991
Tongue
English
Weight
440 KB
Volume
16
Category
Article
ISSN
0340-4285

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Ruthenium(II) complexes of optically act
✍ Hong Yang; NoΓ«l Lugan; RenΓ© Mathieu πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 English βš– 603 KB

The reaction of 2 equiv of the optically active P, N bidentate ligands l-3 with RuC1,(PPh,)3 gives the RuCl,(l-3)2 (4-6) complexes in good yield as a mixture of isomers. The solid state structure of RuC1,( 2), (SC) is described: the two chlorine atoms are in tram position and due to steric crowding,