## Abstract The reaction between hydrogen and pyrites under suitable conditions gives good yields of hydrogen sulphide; practically the whole of the labile sulphur of pyrites can be removed from the ore, leaving ferrous sulphide. Under the conditions described in this paper, the rate of formation o
The manufacture of hydrogen sulphide. Part II. The utilization of the by-product ferrous sulphide from the hydrogen-pyrites reaction
β Scribed by Clark, L. M. ;Spittle, H. M.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1948
- Weight
- 269 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0368-4075
No coin nor oath required. For personal study only.
β¦ Synopsis
Abstract
An investigation of the utilization of the sulphur content of byproduct ferrous sulphide from the hydrogenation of pyrites, is described. The reaction of ferrous sulphide with steam or sulphur dioxide to produce hydrogen sulphide or sulphur is considered to be impracticable. It is shown that the exothermic combustion of ferrous sulphide yields sulphur dioxide in concentrations suitable for sulphuric acid manufacture cither by Chamber or Contact processes. It is at least as easy to burn the ferrous sulphide, obtained as in Part I of this paper, in a smallβscale burner of the handβfired type, as it is to burn pyrites.
π SIMILAR VOLUMES
The infrared chcmilumincscenco arising from the hydrogen abstraction reactions of ELuorinc atoms with 1120, H2S. Ii202 snd CH4 was investignted et low pressure in n ilow apparatus. Emission was found only from the HF product. The rclotive RF vibrational populations were determined under conditions w
~iimiice gniuc Liquid condensnte, gins. . . , . . 360 364 383 Toluene fmct. b.p. 105-l15Β°, gins. . . 04.8 i 2 . 1 tiO.0 Hccd. sylcnc b.11. 1115-18?~. y l s . . . 233.7 "33.7 " l 7 . 3 o/o Toluene frnction on rnw mntrrinl pnesecl . . . . . . . . 10.3 18.0 1 7 4 yo Toluene frnction 011 rnx mntrrial co
## Abstract Anchimerically assisted rearrangement, observed in the fluorination of some Ξ±βamino acids with 70 : 30 (w/w) hydrogen fluoride/pyridine (by weight) in the presence of NaNO~2~, is substantially or fully suppressed by using the less acidic reagent 48 : 52 (w/w) hydrogen fluoride/pyridine.