✦ LIBER ✦

The lowest triplet state of K2Cr2O7. Electron spin resonance in an external magnetic field at 1.2 K

✍ Scribed by W.A.J.A. van der Poel; J. Herbich; J.H. van der Waals

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 719 KB
Volume: 103
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)80002-0

No coin nor oath required. For personal study only.

✦ Synopsis

ESR experunents on the lummescent triplet state of trrclmic KzCT~O, are reported_ For the A site D = 24.300. E = 2 324 GHz. for the B ste D = 26815. E = 3.683 GHz. From the pnnapakxis tirectlon of the ZFS tensor It follows that the excrtatron is loulized on one half of the G20~-ron.

An analyns of spm-orbit coupling m this locaked state IS gnen that accounts for the decay characteristics of the sublevels.

📜 SIMILAR VOLUMES

The lowest triplet state of K2Cr2O7. Opt

The lowest triplet state of K2Cr2O7. Optical spectra and optically detected electron spin resonance at 1.2 K

✍ W.A.J.A. van der Poel; M. Noort; J. Herbich; C.J.M. Coremans; J.H. van der Waals 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 802 KB

Hlgh-resolutron emssion and excitation spectra are reported for a K2C1207 crwtal at 1.2 K, and rhc effect of mmowave saturation on these spectra is dacussed. In the 1-l 2 GHz regon resonances occur at 4.628 and 7.267 CHz, pro~ng that the em&on stems from a tripiet state no) The orzgms of the To-So a

The metastable triplet states of K2Cr2O7

The metastable triplet states of K2Cr2O7 and YVO4 at 1.2 K: Zero-field splitting and lifetimes of the spin components

✍ W. Barendswaard; J. van Tol; J.H. van der Waals 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 504 KB

The zero-field spliltings and IifeGmrs of the phororxciIed IripIeI sxnzs in K2Cr207 and YVO, crys~nls hnvc been derermined by EPR enpcrimenls in zero field. The splilrings for K1Cr2\_07 agree with the spin Hamilronian used previously for describing EPR cxpcrimenw in B magnetic lisld. Those for YVO,

The lowest triplet state of pyrimidine i

The lowest triplet state of pyrimidine in a crystalline host at 1.2 K. The spin-sublevel emission spectra and their vibrational assignment

✍ C.J. Nonhof; J.H. van der Waals 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 452 KB

Spin-sublevel phosphorescence spectra of pyrimidine in benzene are reported• The spectra related to the in-plane spin axes consist of progressions of totally symmetric bands, whereas that of the third sublevel in addition shows strong nontotally symmetric bands. Assignments are given, and some out-o

Pressure-induced change of the hyperfine

Pressure-induced change of the hyperfine interaction in single crystals of FeCl2·4H2O in external magnetic field at 4.2 K

✍ H. Vogel; H. Spiering 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 250 KB

I'reswrc of ==7 kbar apphcd to single crystals of pdramagnctic I-cClz -4Hz0 at 4.2 K and 40 kOe reduces the cffcctwc magnetic field Hcff at the Fe nucleus from 229.5 f 1 to 223.5 f 1 kOe. A decrcasc of the hgand field splitting with prcssure is indlcatcd.

The lowest triplet state of pyrimidine i

The lowest triplet state of pyrimidine in a crystalline host at 1.2 K. Total phosphorescence and Tx sublevel excitation spectra

✍ C.J. Nonhof; J.H. Van Der Waals 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 515 KB

Mössbauer effect and magnetism down to 1

Mössbauer effect and magnetism down to 1.2°K in the triplet ground state of an iron(II)—phenanthroline complex

✍ E. König; B. Kanellakopulos 📂 Article 📅 1972 🏛 Elsevier Science 🌐 English ⚖ 312 KB

Magnetic suswptibilities down to 1.2"K and 57Fe Miissbauer spectra at 42°K are reported on [Fe(pten)2 OR] \* 5H20. The results are consistent with a 3Az(~z~2~~)ground state characterized by a zero-field splitting of D = 4.150 cm-' into an upper !&Ys= +l) and a lower 10) level andg = 2.80. In reasona