The lower excited electronic states of singly and doubly reduced 2,2′-bipyridine
✍ Scribed by E. König; S. Kremer
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- English
- Weight
- 274 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
The electronic spectra of bipy-and bipyz-anions (bipy = 2, P'-bipyridine) have been measured between 5000 and 50 000 cnl-1. The observed bands which have intensities betweenf = 6.30 x lo-2 and f = 0.52 are assised on the basis of HMO and Parker-Parr calculations.
It is well known that 2,2'-bypiridine (bipy)
📜 SIMILAR VOLUMES
Time-resolved ESR spectra have been observed for the lowest triplet states of 2,2'-bipyridine (bpy) and singly protonated bpy (bpyH+) in ethanol at 77 K. With the aid of computer simulation, it is concluded that the T, sublevel is most active in S, +T, intersystem crossing in both molecules studied
Di&ision of Applied Organic Cltentistr~ . CSIRO. G\_P\_O\_ MeIbounte. Victoria 3001. Australia Receired 29 August I979 The absorption spectra of Ru(\_ '.2'-bipl ridine)z (2,2'-bipyridine-1\_4'-dicarbo\vlic acid)\*+ (I) and its diethll ester (II) are \_ JoseI& r&ted 2nd zre both signiftcrtnr& differe