## Abstract Diethyl hydroxyl amine is an efficient trap for alkyl, alkoxy, and peroxy radicals. The specific rate constant for the reaction of ethyl radicals (gas phase, 25Β°C), __tert__βbutoxy radicals (benzene solution, 115Β°C), and poly (peroxystyryl) peroxy radicals (styrene solution, 50Β°C) were
The Low Reactivity of Cyclopropane Derivatives toward Free Radicals
β Scribed by Hammond, George S.; Todd, Robert W.
- Book ID
- 127370746
- Publisher
- American Chemical Society
- Year
- 1954
- Tongue
- English
- Weight
- 431 KB
- Volume
- 76
- Category
- Article
- ISSN
- 0002-7863
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Tert-butoxyl radicals react with indole and methyl substituted derivatives by hydrogen abstraction. For those compounds which are unsubstituted at the N-atom, hydrogen abstraction takes place almost exclusively at the N-H bond. The reactivity of these compounds correlates with their donor electron c