Potential energy curves far the ground state X ' Bgf and for the b "Et state of the hydrogen molecule have been cakulated for internuclear distances 6 4 R Q 12 au. The wavefunctions were represented by 60-term expansions in elliptic coordinates including the interelectronic distance. Improvement ove
The long-range retarded interaction between two hydrogen atoms
โ Scribed by W.J. Deal; R.H. Young
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 199 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0009-2614
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๐ SIMILAR VOLUMES
A general expression is derived for the first-order long-range interaction between atoms with one open shell. An interaction energy decreasing as the inverse fifth power of the distance with a coefficient of 2.0 x lo-51 erg cm5 is predicted for the b 3X-C state of CO, in harmony with an analysis of
The hnmiltonian matrix in the Ritz variational equation js split into the 9mpcrturbedtt and "perturbed" parts. and now mstsix equations are derived. The Pauli principle and symmetry are properly taken into :tccount, The cnkulstcd energies of the intern&ion between the two hydrogen atoms are in good