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The first-order long-range interaction between atoms

โœ Scribed by P.G. Burke; J.H. Tait; A. Dalgarno

Publisher
Elsevier Science
Year
1967
Tongue
English
Weight
143 KB
Volume
1
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

A general expression is derived for the first-order long-range interaction between atoms with one open shell. An interaction energy decreasing as the inverse fifth power of the distance with a coefficient of 2.0 x lo-51 erg cm5 is predicted for the b 3X-C state of CO, in harmony with an analysis of experimental y predissociation data.

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Potential energy curves far the ground state X ' Bgf and for the b "Et state of the hydrogen molecule have been cakulated for internuclear distances 6 4 R Q 12 au. The wavefunctions were represented by 60-term expansions in elliptic coordinates including the interelectronic distance. Improvement ove