๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

The lithium aluminum hydride - aluminum chloride reduction of oximes

โœ Scribed by Mark N. Rerick; Claude H. Trottier; Ranald A. Daignault; John D. DeFoe


Publisher
Elsevier Science
Year
1963
Tongue
French
Weight
251 KB
Volume
4
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


THE reduction of ketoximas and aldoximes with lithium aluminum hydride (LAH) has been reported in numerous instances to give the corresponding primary amine. 1 However, in the reduction of cyclodecanone oxime 2 and in the reduction of certain aryl ketoximes 3 the primary amine was accompanied by an isomeric secondary amine.


๐Ÿ“œ SIMILAR VOLUMES


The rearangement of aromatic aldoximes o
โœ A.E. Petrarca; E.M. Emery ๐Ÿ“‚ Article ๐Ÿ“… 1963 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 211 KB

Although the rearrangement which occurs on reduction of aranat~c ketoximes with lithium aluminum hydride (equation la) Is well known, 192 the reductive rearrangement of aromatic aldoximes under similar conditions (equation lb) has not been reported, despite the fact that a mznber of aldoximes have b

Reduction of alkenes, alkynes and halide
โœ E.C. Ashby; J.J. Lin ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 219 KB

Recently, applications of transition metal hydrides in organic synthesis have received considerable attention. For example, hydrozirconation of alkenes and alkynes to form alkyl and alkenyl intermediates has been shown to have considerable potential for the functionalization of fundamental building