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Reduction of alkenes, alkynes and halides by lithium aluminum hydride - transition metal chloride

โœ Scribed by E.C. Ashby; J.J. Lin

Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
219 KB
Volume
18
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Recently, applications of transition metal hydrides in organic synthesis have received considerable attention. For example, hydrozirconation of alkenes and alkynes to form alkyl and alkenyl intermediates has been shown to have considerable potential for the functionalization of fundamental building blocks in organic chemistry. The reagents NaH-FeClZ* and N~H-RON~-N~(OAC)~~ have also been found to be effective for the reduction of ketones, alkenes and alkynes. Admixtures of LiAlH4-ZrC144 and LiAlH4-TiC14' also have been

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