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The liquid-phase reaction of CCl3 radicals with primary alcohols

✍ Scribed by Liviu Feldman; Zeev B. Alfassi

Publisher: John Wiley and Sons
Year: 1982
Tongue: English
Weight: 358 KB
Volume: 14
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550140608

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✦ Synopsis

Abstract

The kinetics of gamma‐radiation‐induced free‐radical reactions in carbon tetrachloride solutions of ethanol and n‐pentanol were studied in the range of 0.05–0.80__M__ and 25–170°C. The rate constant for the reaction
was found as
The activation energy is larger by 0.8 kcal/mol than for secondary alcohols, while the A~1~ factors are about the same.

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