A Kinetic Study of S-Nitrosothiol Decomp
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Loris Grossi; Pier Carlo Montevecchi
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Article
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2002
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John Wiley and Sons
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English
β 150 KB
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Under anaerobic conditions S-nitrosothiols 1 a Β± e undergo thermal decomposition by homolytic cleavage of the SΓN bond; the reaction leads to nitric oxide and sulfanyl radicals formed in a reversible manner. The rate constants, k 1 , have been determined at different temperatures from kinetic measur