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Metalloprotein-dependent decomposition of S-nitrosothiols: Studies on the stabilization and measurement of S-nitrosothiols in tissues

✍ Scribed by Ali R. Mani; Mohammad R. Ebrahimkhani; Silvia Ippolito; Richard Ollosson; Kevin P. Moore

Book ID
113629894
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
513 KB
Volume
40
Category
Article
ISSN
0891-5849

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## Abstract The kinetics of ketone‐catalyzed decomposition of caroate (peroxomonosulfate) was studied in aqueous alkaline medium at 25Β°C. The rate follows simple second‐order kinetics, first order in each [Ketone] and [PMS]. The rate constant values are independent of hydroxide ion concentrations o