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The kinetics of the thermal bromination of CF3I. Determination of the bond dissociation energy D(CF3−I)

✍ Scribed by Ernest N. Okafo; Eric Whittle

Publisher
John Wiley and Sons
Year
1975
Tongue
English
Weight
538 KB
Volume
7
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

The kinetics of the thermal bromination reaction
have been studied in the range of 173–321°C. For the step
equation image
we obtain
where θ=2.303__RT__ cal/mole. From the activation energy for reaction (11), we calculate that
This is compared with previously published values of D(CF~3~−I). The relevance of the result to published work on k~c~ for a combination of CF~3~ radicals is discussed.

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