Kinetics of some reactions of vinyl and
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Lajos Szirovicza
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Article
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1985
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John Wiley and Sons
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English
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Vinyl and isopropyl radicals were generated by the pyrolysis of azoisopropane in the presence of acrolein at 473-563 K. Reaction products were analyzed by gas chromatography. Rate constant ratios k , / k , = 0.02 lr 0.01 and k 4 / k 3 : 0.01 f 0.005 are suggested for the following reactions: (1) T