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The kinetics of some gas-phase reactions of dimethylsilanone

โœ Scribed by Davidson, Iain M. T.; Fenton, Andrew.


Book ID
125512752
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
428 KB
Volume
4
Category
Article
ISSN
0276-7333

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Kinetics of some reactions of vinyl and
โœ Lajos Szirovicza ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 539 KB

Vinyl and isopropyl radicals were generated by the pyrolysis of azoisopropane in the presence of acrolein at 473-563 K. Reaction products were analyzed by gas chromatography. Rate constant ratios k , / k , = 0.02 lr 0.01 and k 4 / k 3 : 0.01 f 0.005 are suggested for the following reactions: (1) T