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The kinetics of slow-initiated living polymerizations

✍ Scribed by D.C. Pepper

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
326 KB
Volume
16
Category
Article
ISSN
0014-3057

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✦ Synopsis

Equations permitting derivation of initiation and propagation rate constants in non-ideal living polymerizations are presented. Earlier formulations are compared, simplified and tested against experimental data for the polymerizations of n-vinyl carbazole and n-butyl cyanoacrylate. Novel cases having more complex initiation processes (in the polymerization of cyanoacrylates by amines) are formulated and tested.

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