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Mechanisms and kinetics of living radical polymerizations

โœ Scribed by Takeshi Fukuda; Atsushi Goto; Kohji Ohno


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
196 KB
Volume
21
Category
Article
ISSN
1022-1336

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Iniferters are initiators that induce radical polymerization that proceeds via initiation, propagation, primary radical termination, and transfer to initiator. Because bimolecular termination and other transfer reactions are negligible, these polymerizations are performed by the insertion of the mon

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The radical homopolymerization of sodium acrylate in water in the presence of potassium peroxodisulphate as initiator was investigator through the use of conductimetry and dilatometry. The kinetics were monitored while varying either the monomer concentration or temperature. Initial rate and order o