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The kinetics of radical polymerization—XXV: Study of the radical reactivity of substituted nitrobenzenes—I

✍ Scribed by T. Földes-Berezhnykh; S. Szakács; F. Tüdős


Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
503 KB
Volume
8
Category
Article
ISSN
0014-3057

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The kinetics of radical polymerization—X
✍ T. Földes-Berezhnykh; F. Tüdős; S. Szakács 📂 Article 📅 1972 🏛 Elsevier Science 🌐 English ⚖ 415 KB

A study was made of the radical reactivities of substituted nitrobenzenes where, in addition to the inductive effect, a mesomeric effect is exerted by the substituent on the reactivity of the nitro group. Investigation of the relative intensity of the mesometic effect showed that the mesomeric effec

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A study was made on the inhibition by some 3,3'-and 4,4'-disubstituted azobenzenes of the polymerization of vinylacetate initiated by azoisobutyronitrile at 50 °. The inhibitory effects of these substances can be attributed to their ability to engage in radical addition giving a less reactive hydraz