The kinetics of oxidation of allyl alcohol with potassium bromate in the presence of osmium(VIII) catalyst in aqueous acid medium has been studied under varying conditions. The active species of oxidant and catalyst in the reaction were understood to be and ## Ϫ Bro 3 H 2 OsO 5 , respectively. Th
The kinetics of oxidation of secodary alcohols by potassium bromate
✍ Scribed by R. Natarajan; W. Venkatasubramanian
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- French
- Weight
- 168 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
As part of e comprehensive scheme on the oxidation mechanisms of organic substrates by various oxidants, we investigated the kinetics of the oxidation of secondary alcohols by potassium bromate. Conventionally one uses this
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The kinetics of oxidation of gallic acid with potassium bromate in the presence of vanadiurn(V) catalyst in aqueous acid medium has been studied under varying conditions. The active species of catalyst and oxidant in the reaction were understood to be HBrO, and VO,+ The autocatalysis exhibited by o
## Abstract The oxidation of α‐hydroxy acids and α‐hydroxy ketones by Br(V) follows the rate‐law However, the former reaction exhibits a second‐order dependence on hydrogen ion concentration while the latter reaction has a third‐order dependence. A mechanism involving a slow formation of a bromate