𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The kinetics of oxidation of secodary alcohols by potassium bromate

✍ Scribed by R. Natarajan; W. Venkatasubramanian


Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
168 KB
Volume
10
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis


As part of e comprehensive scheme on the oxidation mechanisms of organic substrates by various oxidants, we investigated the kinetics of the oxidation of secondary alcohols by potassium bromate. Conventionally one uses this


📜 SIMILAR VOLUMES


Kinetics of osmium(VIII) catalyzed oxida
✍ S. M. Desai; N. N. Halligudi; S. T. Nandibewoor 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 139 KB 👁 2 views

The kinetics of oxidation of allyl alcohol with potassium bromate in the presence of osmium(VIII) catalyst in aqueous acid medium has been studied under varying conditions. The active species of oxidant and catalyst in the reaction were understood to be and ## Ϫ Bro 3 H 2 OsO 5 , respectively. Th

Kinetics of vanadium (V) catalyzed oxida
✍ Dasharath L. Kamble; Sharanappa T. Nandibewoor 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 381 KB 👁 2 views

The kinetics of oxidation of gallic acid with potassium bromate in the presence of vanadiurn(V) catalyst in aqueous acid medium has been studied under varying conditions. The active species of catalyst and oxidant in the reaction were understood to be HBrO, and VO,+ The autocatalysis exhibited by o

A kinetic study of the oxidation of α-hy
✍ R. Natarajan; N. Venkatasubramanian 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 English ⚖ 346 KB

## Abstract The oxidation of α‐hydroxy acids and α‐hydroxy ketones by Br(V) follows the rate‐law However, the former reaction exhibits a second‐order dependence on hydrogen ion concentration while the latter reaction has a third‐order dependence. A mechanism involving a slow formation of a bromate