The kinetics of olation of some hydroxoaquotetrammine-cobalt(III) complexes in the solid state
β Scribed by P.R. Nambiar; W.W. Wendlandt
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 291 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0040-6031
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π SIMILAR VOLUMES
## Abstract The mathematical solution of the equations derived from a kinetic scheme previously developed for donorβacceptor complex polymerization was based on steadyβstate conditions and the applicability of initial concentration conditions over a range of conversion. These assumptions are scruti
Aquation rates for cis-CoCl(en)2(A)2+ (A = 3,5-lutidine, imidazole, N-methylimidazole, benzimidazole) have been determined by halide release titration in 1 .O M HNOz at 50-80Β°C. Kinetic parameters are (in the above order of A) 1O7k29s (sec-I), 7.4, 5.7, 1.3, 9.7; E, (kJ/mole), 103, 101, 130, 112; lo