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The resolution of some chloro(amine)bis(ethylenediamine)cobalt(III) complexes

โœ Scribed by I.J. Kindred; D.A. House


Publisher
Elsevier Science
Year
1974
Weight
222 KB
Volume
10
Category
Article
ISSN
0020-1650

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## Abstract Kinetics of reduction of the surfactant complex ions, __cis__โ€chloro/bromo (dodecylamine)bis(ethylenediamine)cobalt(III) by iron(II) in aqueous solution was studied at 303, 308, and 313 K by spectrophotometry method under pseudoโ€firstโ€order conditions, using an excess of the reductant.

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## Abstract Oxygenation of solutions containing bis(ethylenediamine) cobalt(II) ions leads to a mixture of diastereomeric forms of ฮผโ€peroxoโ€ฮผโ€hydroxoโ€bis[bis(ethylenediamine) cobalt(III)] cations. The existence of a mesoโ€isomer has now been proved by its isolation as perchlorate and by an Xโ€ray str