The kinetics of Mn(II)-catalysed ozonation of oxalic acid in aqueous solution
β Scribed by R. Andreozzi; A. Insola; V. Caprio; M.G. D'Amore
- Book ID
- 119016038
- Publisher
- IWA Publishing
- Year
- 1992
- Tongue
- English
- Weight
- 326 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0043-1354
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π SIMILAR VOLUMES
Manganese-catalysed ozonation of glyoxalic acid in aqueous solutions has been investigated in the pH range 2.0Β±4.0. The addition of manganese ions (Mn(II) or Mn(IV)) to a glyoxalic acidΒ±ozone system allows the substrate to be oxidized through a mechanism different from that reported for uncatalysed
## Abstract The paper presents an analysis of the results of spectroscopic studies obtained in the ultraviolet range UV for unsaturated ammonium oxalate solutions containing Mn(II) impurity __c__~i~. The aim is to follow manganese oxalate formation processes at different ammonium oxalate concentrat
Heterogeneous catalysis by MnO 2 of oxalic acid ozonation in aqueous solution has been investigated in the pH range 3.2-7.0. The influence of catalyst load and reaction temperature upon rate development of the ozonation process has also been examined. The observed dependence of system reactivity on