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The use of manganese dioxide as a heterogeneous catalyst for oxalic acid ozonation in aqueous solution

✍ Scribed by R. Andreozzi; A. Insola; V. Caprio; R. Marotta; V. Tufano


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
307 KB
Volume
138
Category
Article
ISSN
0926-860X

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✦ Synopsis


Heterogeneous catalysis by MnO 2 of oxalic acid ozonation in aqueous solution has been investigated in the pH range 3.2-7.0. The influence of catalyst load and reaction temperature upon rate development of the ozonation process has also been examined. The observed dependence of system reactivity on pH and the results obtained by ozonation experiments with MnO 2 catalysts of different pHzm values agree with a reaction mechanism involving the formation of a surface Mnoxalic acid complex.


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