Supercritical carbon dioxide was found to be a suitable substitute for halogenated organic solvents in its copolymerization with propylene oxide. The system was studied utilizing a heterogenous catalyst, zinc glutarate. The polymers were analyzed for selectivity in polycarbonate linkages by 'H NMR s
The use of manganese dioxide as a heterogeneous catalyst for oxalic acid ozonation in aqueous solution
β Scribed by R. Andreozzi; A. Insola; V. Caprio; R. Marotta; V. Tufano
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 307 KB
- Volume
- 138
- Category
- Article
- ISSN
- 0926-860X
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β¦ Synopsis
Heterogeneous catalysis by MnO 2 of oxalic acid ozonation in aqueous solution has been investigated in the pH range 3.2-7.0. The influence of catalyst load and reaction temperature upon rate development of the ozonation process has also been examined. The observed dependence of system reactivity on pH and the results obtained by ozonation experiments with MnO 2 catalysts of different pHzm values agree with a reaction mechanism involving the formation of a surface Mnoxalic acid complex.
π SIMILAR VOLUMES
The potential of Γy ash procured form coal-Γred thermal power plants was studied as a heterogeneous catalyst in the oxidation of aqueous sodium sulΓde solutions with hydrogen peroxide in the temperature range of 303Γ323 K. The e β ects of various parameters (source of Γy ash, Γy ash loading, initial