The kinetics of hydrolytic polymerization of ϵ-caprolactam. IV. Theoretical aspect of the molecular weight distribution
✍ Scribed by Kazuo Tai; Yoshihiro Arai; Hiroichi Teranishi; Takashi Tagawa
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- English
- Weight
- 211 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0021-8995
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## Abstract The concentrations of the cyclic oligomers (__C__~__i__~; __i__ = 3, 4, 5, and 6) in the polymeric products of ε‐caprolactam were determined by high‐performance liquid chromatography. The equilibrium data on the oligomers were obtained as a function of the polymerization temperature and
## Abstract A kinetic scheme for the single‐centre mechanism of addition polymerization has been considered. The propagation and termination rates are considered as depending both on the chain length and conversion. The relation of the molecular weight distribution in equilibrium processes is gener