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Molecular weight distribution analysis of the mechanisms of addition polymerization

โœ Scribed by V. V. Shamanin

Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
400 KB
Volume
31
Category
Article
ISSN
0323-7648

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โœฆ Synopsis

Abstract

A kinetic scheme for the singleโ€centre mechanism of addition polymerization has been considered. The propagation and termination rates are considered as depending both on the chain length and conversion. The relation of the molecular weight distribution in equilibrium processes is generalized for application to the nonโ€equilibrium ones. A method for the investigation of the multicentreโ€addition polymerization processes is presented.

๐Ÿ“œ SIMILAR VOLUMES

Polymerization mechanisms and molecular
Polymerization mechanisms and molecular weight distributions. III. Gamma-radiation-initiated polymerization of methyl methacrylate
โœ Jorma G. Braks; Gunter Mayer; Robert Y. M. Huang ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 339 KB

## Abstract The termination mechanism in gammaโ€radiationโ€initiated polymerization of methyl methacrylate was investigated. The termination mechanism and the associated rate constants were determined by comparing the theoretical molecular weight distribution (MWD) and the experimental MWD, which was