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The kinetics of dimerization of chlorotrifluoroethene

✍ Scribed by Bernard Atkinson; Christos Tsiamis

Publisher
John Wiley and Sons
Year
1979
Tongue
English
Weight
340 KB
Volume
11
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

Rate constants determined for the thermal dimerization of chlorotrifluoroethene to dichlorohexafluorocyclobutane at 404–672 K have been correlated with previously published results. For the temperature range of 404–800 K,

The dependence of the preexponential factor on temperature corresponds to a value of 17 J/KΒ·mol for the difference in heat capacity (Ξ”__C__~p~^Β±^) between the activation complex and the reactant.

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