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The kinetics and the mechanism of the thermal decomposition of bis(trifluoromethyl) trioxide. The influence of carbonmonoxide on its decomposition

✍ Scribed by J. Czarnowski; H. J. Schumacher

Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
398 KB
Volume
13
Category
Article
ISSN
0538-8066

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✦ Synopsis

The kinetics of the thermal decomposition of CF303CF3 has been investigated in the pressure range of 15599 torr at temperatures between 59.8 and 90.3OC and also in the presence of CO between 42 and 7Β°C. The reaction is homogeneous. In the absence of CO the only reaction products are CF302CF3 and 0 2 . The rate of reaction is strictly proportional to the trioxide pressure, and is not affected by the total pressure, the presence of inert gases, and oxygen.

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