The rate of dissolution of rotating copper discs in acidified copper(H) solutions prepared in an acetonitrile-water solvent (mole fraction acetonitrile = 0.25) was measured in the temperature range 27C-360K. The rate of dissolution was found to be proportional to the square root of the rotation spee
The kinetics and mechanism of the corrosion of copper in acidified copper (II) bromide solution
β Scribed by D.Brynn Hibbert; Steven Richards; Valerie Gonzalves
- Book ID
- 115846991
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 487 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0010-938X
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The reaction of copper with benzyl bromides in hexamethylphosphoramide has been studied. The kinetic and thermodynamic parameters of the reaction have been obtained. Hammett plots of log (__k__/__k__^o^) vs the substituent constant Ο gave good correlations (Ο = 0.15, __S__~Ο~ = 0.02, __
The reaction of copper metal with various substituted benzyl bromides in dimethylformamide has been studied and the kinetic and thermodynamic parameters of the reaction have been obtained. Hammett plots of log(k/k β’ ) vs the substituent constant Ο gave good correlations (Ο = 0.24, S Ο = 0.03, r = 0.