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The kinetics and mechanism of radiation-chemical liquid-phase chlorination of unsymmetrical difluoroethane

✍ Scribed by I. R. Begishev; V. A. Poluéktov

Book ID
112358936
Publisher
Springer
Year
1979
Tongue
English
Weight
314 KB
Volume
14
Category
Article
ISSN
0040-5760

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The first stage thermal reactions of CFzCICH, in the presence of chlorine have been studied between 554 and 614 K. These are c12 CFZClCH, -CFZCH, + HCI and CF,ClCH, + CI;! CFZClCH&l + HCI Rate equations derived from a radical mechanism are shown to fit the experimental results. Values of Arrhenius p